This is seen in three separate phase fields for the three phases in the water P-T diagram: Solid (ice) Liquid (water) Vapour (steam) FIGURE 2.7: SCHEMATIC P-T DIAGRAM FOR WATER Two phases can co-exist over a range of different temperature-pressure values but these are not independent: fixing the pressure fixes the temperature at which the phases can co-exist. A single phase can exist over a range of temperature and pressure. In a unary system, there is only one component, so the axes of the phase diagram are pressure and temperature - composition is constant. Such information is vital in understanding the stability of materials and the effects of any processing route on the materials microstructure. They may be used to predict what phases will be seen at equilibrium in a system from a knowledge of composition, temperature and pressure.
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